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General Chemistry · MCAT

MCAT General Chemistry: Stoichiometry and Solutions

Limiting reagent calculations, molarity and molality, and colligative properties tested on the MCAT.

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What is a limiting reagent?
The reactant that is fully consumed first, limiting how much product can form.
What is an excess reagent?
A reactant that remains partially unreacted after the limiting reagent is used up.
What is theoretical yield?
The maximum amount of product predicted from the limiting reagent using stoichiometry.
What is actual yield?
The amount of product actually obtained from an experiment or reaction.
Percent yield is calculated as ____.
(actual yield / theoretical yield) x 100%
In a limiting reagent problem, what is the first step after writing a balanced equation?
Convert the mass (or volume) of each reactant into moles.
How do you identify the limiting reagent once the moles of each reactant are known?
Divide each reactant's moles by its stoichiometric coefficient; the smallest result identifies the limiting reagent.
Where do the mole ratios used in a stoichiometry calculation come from?
The coefficients of the balanced chemical equation.
What is Avogadro's number?
6.022 x 10^23 particles per mole.
What is molar mass?
The mass in grams of one mole of a substance.
What is an empirical formula?
The simplest whole-number ratio of atoms of each element in a compound.
What is a molecular formula?
The actual number of atoms of each element in one molecule of a compound.
How is a molecular formula related to its empirical formula?
The molecular formula equals the empirical formula multiplied by a whole number n.
What is percent composition by mass?
The mass of one element divided by the total mass of the compound, times 100%.
What law guarantees that the mass of reactants equals the mass of products?
The law of conservation of mass.

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