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General Chemistry · MCAT

MCAT General Chemistry: Acid-Base Chemistry and Buffers

Bronsted-Lowry and Lewis acid-base theory, pH and pOH calculations, and buffer system concepts tested on the MCAT.

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What is the Bronsted-Lowry definition of an acid?
A proton (H+) donor
What is the Bronsted-Lowry definition of a base?
A proton (H+) acceptor
What is the Lewis definition of an acid?
An electron pair acceptor
What is the Lewis definition of a base?
An electron pair donor
What is the formula relating pH to hydrogen ion concentration?
pH = -log[H+]
What is the formula relating pOH to hydroxide ion concentration?
pOH = -log[OH-]
What is the relationship between pH and pOH at 25 degrees Celsius?
pH + pOH = 14
What is the value of Kw, the ion product of water, at 25 degrees Celsius?
1.0 x 10^-14
What is a conjugate base?
The species formed after an acid donates a proton
What is a conjugate acid?
The species formed after a base accepts a proton
Name a common strong acid used in general chemistry problems.
Hydrochloric acid (HCl)
Name a common strong base used in general chemistry problems.
Sodium hydroxide (NaOH)
What does the equilibrium constant Ka describe?
The strength of a weak acid, based on its degree of dissociation in water
What does the equilibrium constant Kb describe?
The strength of a weak base, based on its degree of dissociation in water
What is the relationship between Ka and Kb for a conjugate acid-base pair?
Ka x Kb = Kw

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