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General Chemistry · MCAT

MCAT General Chemistry: Atomic Structure and Periodic Trends

Electron configuration, quantum numbers, and periodic trends (atomic radius, ionization energy, electronegativity) tested on the MCAT.

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What does the principal quantum number (n) describe?
The main energy level (shell) of an electron and its average distance from the nucleus.
What does the azimuthal (angular momentum) quantum number (l) describe?
The shape of an electron's subshell.
What is the allowed range of values for the azimuthal quantum number l, given principal quantum number n?
Any integer from 0 to n minus 1.
What does the magnetic quantum number (ml) describe?
The orientation of an orbital in space.
What is the allowed range of values for the magnetic quantum number ml, given l?
Any integer from negative l to positive l, including zero.
What does the spin quantum number (ms) describe?
The intrinsic spin direction of an electron.
What are the two possible values of the spin quantum number ms?
+1/2 and -1/2
Which subshell letter corresponds to l = 0?
s
Which subshell letter corresponds to l = 1?
p
Which subshell letter corresponds to l = 2?
d
Which subshell letter corresponds to l = 3?
f
What is the maximum number of electrons that can occupy an s subshell?
2
What is the maximum number of electrons that can occupy a p subshell?
6
What is the maximum number of electrons that can occupy a d subshell?
10
What is the maximum number of electrons that can occupy an f subshell?
14

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