Chemistry · AP

AP Chemistry: Kinetics and Equilibrium

AP Chemistry reaction rates, rate laws, and equilibrium concepts including Le Chatelier's principle.

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What is reaction rate?
The change in concentration of a reactant or product per unit time.
Name four factors that affect reaction rate.
Concentration, temperature, surface area, and presence of a catalyst.
How does increasing concentration affect reaction rate?
It increases the collision frequency between molecules, raising the reaction rate.
How does temperature increase reaction rate?
It increases the average kinetic energy of molecules and their collision frequency.
What is a catalyst?
A substance that increases the reaction rate without being consumed in the reaction.
What is activation energy (Ea)?
The minimum energy required for reactant molecules to overcome and form products.
How does increasing surface area affect reaction rate?
It increases the number of particles available for collision with other reactants.
What does collision theory require for a reaction to occur?
Molecules must collide with the correct orientation and sufficient energy.
What does 'collision orientation' mean in kinetics?
The proper spatial arrangement of atoms in colliding molecules needed for a successful reaction.
How does temperature relate to collision frequency?
Higher temperature causes molecules to move faster and collide more frequently.
What is a rate law?
A mathematical equation relating the reaction rate to the concentrations of reactants, each raised to a power.
What does 'order' mean in a rate law?
The exponent of a concentration term in the rate law expression.
How is overall reaction order determined?
By adding all the exponents (orders) of the concentration terms in the rate law.
What is unique about the half-life of a first-order reaction?
The half-life is constant and independent of the initial concentration.
What is true about zero-order reaction rates?
The rate remains constant as the concentration changes; rate is independent of concentration.

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