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Chemistry · AP

AP Chemistry: Gases and Solutions

Gas laws, solution concentration, and colligative properties tested on AP Chemistry. Front: the law, term, or formula. Back: definition or formula with a brief usage note.

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Boyle's Law
At constant temperature, pressure and volume of a gas are inversely proportional: PV = constant
Charles's Law
At constant pressure, volume and absolute temperature of a gas are directly proportional: V/T = constant
Gay-Lussac's Law
At constant volume, pressure and absolute temperature of a gas are directly proportional: P/T = constant
Combined Gas Law
PV/T = constant for a fixed amount of gas, combines Boyle's and Charles's Laws
Ideal Gas Law
PV = nRT, where P is pressure, V is volume, n is moles, R is the gas constant, T is absolute temperature
Gas constant R value
0.0821 L·atm/(mol·K) or 8.314 J/(mol·K), depending on units
Dalton's Law of Partial Pressures
The total pressure of a gas mixture equals the sum of the partial pressures of each individual gas: P(total) = P1 + P2 + P3...
Graham's Law of Effusion
The rate of effusion of a gas is inversely proportional to the square root of its molar mass: rate1/rate2 = sqrt(M2/M1)
Molarity
Moles of solute per liter of solution, M = n/V, the most common concentration unit in AP Chemistry
Molality
Moles of solute per kilogram of solvent, m = n/kg solvent, does not change with temperature
Normality
Equivalents of solute per liter of solution, N = eq/V, often used for acids and bases
Parts per million (ppm)
Mass of solute per million parts of solution, ppm = (mass solute / mass solution) × 10^6, used for dilute solutions
Dilution equation
M1V1 = M2V2, where subscripts 1 and 2 represent initial and final states
Vapor pressure lowering
The vapor pressure of a solution is lower than pure solvent due to the presence of nonvolatile solute particles
Raoult's Law
P(solution) = X(solvent) × P°(solvent), where X is mole fraction and P° is pure solvent vapor pressure

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