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Physical and Analytical Chemistry · College · College and University

Electrochemistry and Materials Chemistry

Galvanic cells, Nernst equation, batteries, corrosion, solid state structures, semiconductors and nanomaterials.

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35 basic cards for College Physical and Analytical Chemistry. It opens with "What is a galvanic cell?" and "At which electrode in a galvanic cell does oxidation occur?". Study it alongside the other College sets below.

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What is a galvanic cell?
Show answerAn electrochemical cell that spontaneously produces electrical current from a redox reaction
At which electrode in a galvanic cell does oxidation occur?
Show answerAt the anode
At which electrode in a galvanic cell does reduction occur?
Show answerAt the cathode
What is the function of a salt bridge in a galvanic cell?
Show answerIt allows anions and cations to migrate between compartments to maintain electrical neutrality
What formula relates standard cell potential to reduction potentials?
Show answerE(cell) = E(cathode) - E(anode)
When is a redox reaction spontaneous in a galvanic cell?
Show answerWhen E(cell) is positive
What does the Nernst equation relate?
Show answerThe relationship between cell potential and the concentrations of reactants and products
What is the Nernst equation at 25 degrees Celsius?
Show answerE = E(0) - (0.0592 V / n) log(Q)
In the Nernst equation, what does Q represent?
Show answerThe reaction quotient, the ratio of product concentrations to reactant concentrations
How does temperature affect the coefficient in the Nernst equation?
Show answerIt increases with temperature, becoming approximately 0.0615 V at 37 degrees C instead of 0.0592 V
What is E(cell) equal to when Q equals K?
Show answerZero, because the system is at equilibrium
What is the main difference between primary and secondary batteries?
Show answerPrimary batteries are non-rechargeable, secondary batteries can be recharged
What is the standard EMF of an alkaline battery?
Show answer1.5 V
In a lead-acid battery, what material forms the negative electrode?
Show answerLead (Pb)
In a lead-acid battery, what material forms the positive electrode?
Show answerLead dioxide (PbO2)

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