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College Physics: Thermodynamics

Laws of thermodynamics, heat engines, and entropy concepts for a college physics sequence.

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41 basic cards for College Physics. Set 4 of 5 in College Physics. It opens with "What does the First Law of Thermodynamics state?" and "Write the First Law of Thermodynamics as an equation". Study it alongside the other College sets below.

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What does the First Law of Thermodynamics state?
Show answerEnergy cannot be created or destroyed, only converted from one form to another. In a system, the change in internal energy equals heat added minus work done by the system.
Write the First Law of Thermodynamics as an equation.
Show answerΔU = Q - W, where ΔU is change in internal energy, Q is heat added to the system, and W is work done by the system.
Define internal energy in a thermodynamic system.
Show answerThe total energy contained within a system due to the random motion of its molecules, excluding macroscopic kinetic and potential energy.
Define entropy.
Show answerA measure of the disorder or randomness in a system, related to the number of microscopic states a system can occupy at a given macroscopic condition.
What does the Third Law of Thermodynamics state?
Show answerThe entropy of a perfect crystal at absolute zero (0 K) is zero. As temperature approaches absolute zero, entropy approaches a constant minimum.
State the Zeroth Law of Thermodynamics.
Show answerIf two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium with each other. This defines temperature as a fundamental quantity.
What is absolute zero in Kelvin?
Show answer0 K, which equals approximately -273.15 degrees Celsius or -459.67 degrees Fahrenheit.
Define a reversible process in thermodynamics.
Show answerA process where the system remains in equilibrium throughout and can be reversed by infinitesimal changes to external conditions, returning both system and surroundings to initial states.
Define an irreversible process in thermodynamics.
Show answerA real process where the system is not in equilibrium and cannot be reversed to return both system and surroundings to their initial states.
What is heat in thermodynamics?
Show answerEnergy transfer between a system and its surroundings due to a temperature difference. Heat flows spontaneously from higher to lower temperature.
What is work in thermodynamics?
Show answerEnergy transfer due to a force acting through a distance. In thermodynamics, it typically refers to expansion or compression work done by or on a gas.
What is an isothermal process?
Show answerA thermodynamic process where temperature remains constant throughout. For an ideal gas, ΔU = 0, so Q = W.
What is an adiabatic process?
Show answerA thermodynamic process where no heat is exchanged between the system and surroundings (Q = 0). Work done equals the change in internal energy (W = -ΔU).
What is an isobaric process?
Show answerA thermodynamic process at constant pressure. The work done by the gas is W = P times ΔV.
What is an isochoric (isovolumetric) process?
Show answerA thermodynamic process at constant volume (ΔV = 0). No work is done by or on the gas (W = 0).

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